RELATIONS BETWEEN GRANITES AND PEGMATITES
At the pegmatitic stage, some elements that exist in the ppm range at the source become sufficiently concentrated to precipitate minerals of their own, e.g., as spodumene (Li), beryl (Be), pollucite, (Cs), cassiterite (Sn), and tantalite (Ta). Using melting relations and element partitioning, then, we can predict the concentration of a particular trace element at the beginning of
granite magmatism and at the end pegmatitic stage (e.g., London et al., 1999). This allows us to model and answer an important and recurring question in the relations between
granites and pegmatites how much crystal fractionation must take place from anatexis to produce a pegmatite capable of precipitating spodumene, beryl, etc. (Fig. 2)? Most of our work has been on the elements of Groups IA (alkalis: Li, Na, K, Rb, and Cs) and IIA (alkaline earths: Be, Ca, Sr, and Ba the behavior of Mg during crystal fractionation is sufficiently well understood).
We have also studied the behavior of added components to the
granite system that may influence partitioning behavior. These include the important fluxes and ligands of boron (B), fluorine (F), and phosphorus (P). Like many of the economically important specialty metals, these ligands behave incompatibly in felsic crystal-melt systems and hence both are concentrated together in
granite and pegmatite ore deposits. The association is so strong, e.g., between Sn and B, that many economic geologists presume that the specialty metal and exotic ligand form a stable complex in melt, and that this complex itself is responsible for incompatibility and concentration toward the ends stages of magmatism.

Figure 2. Fractionation of an incompatible trace element (purple sphere), from anatexis to saturation in melt. (A) The trace element signature of melt is controlled by partitioning between residual minerals and melt. (B) The trace element signature of melt is modified by fractional crystallization from the melt. (C) increasing concentration of the trace element finally achieves saturation of melt and precipitation of a mineral in which the trace element is an essential constituent, e.g,. Be in beryl.
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